You cannot in general put a group structure on a set. There is a model of ZF with a set A that has no infinite countable subset and cannot be partitioned into finite sets; such a set has no group structure.
See e.g at http://groups.google.com/group/sci.math/msg/06eba700dfacb6ed
Sketch of proof that in standard Cohen model the set A=an:ninomegaA=an:ninomega of adjoined Cohen reals cannot be partitioned into finite sets:
Let mathbbP=Fn(omegatimesomega,2)mathbbP=Fn(omegatimesomega,2) which is the poset we force with. The model is the symmetric submodel whose permutation group on mathbbPmathbbP is all permutations of the form pi(p)(pi(m),n)=p(m,n)pi(p)(pi(m),n)=p(m,n) where pipi varies over all permutations of omegaomega, (that is we are extending each pipi to a permutation of mathbbPmathbbP which I also refer to as pipi) and the relevant filter is generated by all the finite support subgroups.
Suppose for contradiction that pVdash"bigcupiinIdotAi=ApVdash"bigcupiinIdotAi=A is a partition into finite pieces"; let EE (a finite set) be the support of this partition. Take some ai0notinEai0notinE and extend pp to a qq such that qVdash‘‘ai0,ldotsainqVdash‘‘ai0,ldotsain is the piece of the partition containing ai0ai0". Then pick some jj which is not in EE nor the domain of qq nor equal to any of the ai0,ldotsailai0,ldotsail. If pipi is a permutation fixing EE and each of ai1,ldotsainai1,ldotsain and sending ai0ai0 to ajaj, it follows that pi(q)Vdash"aj,ai1,ldotsainpi(q)Vdash"aj,ai1,ldotsain is the piece of the partition containing a_j". But also qq and pi(q)pi(q) are compatible and here we run into trouble, because qq forces that ai0ai0 and ai1ai1 are in the same piece of the partition, and pi(q)pi(q) forces that this is not the case (and they are talking about the same partition we started with because pipi fixes EE). Contradiction.
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