heat - What Makes Stars Hot?

Stars do not get hot because of nuclear fusion, they become hot enough to sustain nuclear fusion and this process maintains their temperatures. Nuclear fusion actually stops a star getting hotter.

Protostars (before nuclear fusion) get hot because of a well known statistical relationship between the gravitational potential energy of a gas and the internal kinetic energy of the particles that make up the gas. [In an ideal gas, the kinetic energy of the particles is directly proportional to the temperature of the gas.] This is known as the virial theorem, which says that twice the summed kinetic energy of particles ($K$) plus the gravitational potential energy ($Omega$, which is a negative quantity for a bound object) equals zero.
$$ 2K + Omega = 0$$

Now you can write down the total energy of the system as
$$ E_{tot} = K + Omega$$
and hence from the virial theorem that
$$E_{tot} = frac{Omega}{2},$$
which is also negative.

If we now remove energy from the system, for instance by allowing the gas to radiate away energy, such that $Delta E_{tot}$ is negative, then we see that
$$Delta E_{tot} = frac{1}{2} Delta Omega$$

So $Omega$ becomes more negative - which is another way of saying that the protostar attains a more collapsed configuration.

Oddly, at the same time, we can use the virial theorem to see that
$$ Delta K = -frac{1}{2} Delta Omega = -Delta E_{tot}$$
is positive. i.e. the kinetic energies of particles in the gas (and hence their temperatures) actually become hotter. In other words, the gas has a negative heat capacity. But a hotter temperature usually means more radiation is produced and if the energy losses continue, then so does the collapse.

This process is ultimately arrested in a star by the onset of nuclear fusion. This replaces the radiative losses with nuclear energy and the star attains a quasi-equilibrium that lasts as long as it has nuclear fuel to burn.