I would like to risk an answer that does not use the language of algebraic geometry. For a pair (complex analytic variety $X$; closed analytic subvariety $Y$), $U=Xsetminus Y$,
there exists a triangulation such that $Y$ is a subcomplex (see, for example Triangulations of algebraic sets - Hironaka 1974, can be found with google books). In other words $X$ is a simplicial complex, and $Y$
is a subcomplex. Now, if $X$ is normal its singularities are in real codimension at least $4$. I.e. $X$ is a $PL$ manifold in codimension $4$.
In order to show that the fundamental group of $Xsetminus Y$ surjects onto the fundamental group of $X$, it is sufficient to show that every loop in $X$ can be homotoped into $Xsetminus Y$. Since $Y$ it is contained in the simplicial subcomplex of codimension $2$ it is enough to show that any loop in $X$ can be homotoped so it does not touch any simplex of codim $2$, but this is true for every $PL$ space that is a manifold in codim $2$.
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