Even if you ask that induces trivial maps on all (singular) homology and cohomology groups, there are still easy manifold examples. (This actually arises as an exercise in Hatcher's AT).
For instance, let be the composition , where the map from to is simply collapsing the 2-skeleton to a point, and the map from to is the Hopf map.
As others have mentioned, since is a , if follows that induces trivial maps on homotopy groups.
Since the Hopf map induces trivial maps on homology and cohomology, it follows that does as well.
Finally, to see that is NOT nullhomotopic, assume it is. Since the map from to is a fiber bundle, it has the homotopy lifting property. Hence, we can lift the homotopy of to a homotopy where is the above map from to and is is a map from to , the preimage of a point in under the Hopf map.
But has degree 1, while has degree 0, a contradiction.
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